Near-IR luminescent neodymium complexes: spectroscopic probes for hydroamination catalysis.
نویسندگان
چکیده
Neodymium complexes bearing the sensitising bis(oxazolinylphenyl)amine (BOPA) ligands have been prepared, and analysed spectroscopically under both catalytic and pseudo-catalytic conditions with respect to the intramolecular hydroamination of an aminoalkene, providing a direct means of monitoring binding events and relative space around the metal centre.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 54 شماره
صفحات -
تاریخ انتشار 2013